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Crumpled Fabric

Rare Earth Minerals: Economic Extraction Analysis and Ranking

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Key Points

  1. Bastnasite, monazite, and ion-adsorption clays account for 95% of global rare earth production

  2. China dominates the rare earth supply chain with 60% of mining and 90% of processing capacity

  3. Environmental challenges include radioactive waste management and chemical pollution



Rare Earth in Bayan Obo / NASA Earth Observatory
Rare Earth in Bayan Obo / NASA Earth Observatory

Rare earth elements (REEs) are a group of 17 elements comprising 15 lanthanides plus scandium and yttrium. Despite their name, most REEs are relatively abundant in the Earth's crust, but they rarely occur in concentrated, economically viable deposits. Their unique electronic, optical, and magnetic properties make them essential components in over 200 products, including high-tech consumer electronics, electric vehicles, wind turbines, and defense technologies.

This analysis examines the primary minerals that serve as sources for rare earth elements, focusing on their economic extraction characteristics, processing methodologies, and global production patterns. The minerals are ranked according to their commercial importance and frequency of use in REE extraction.

Mineral Rankings by Economic Importance and Extraction Frequency

Based on the available research materials, the following ranking represents the relative importance of minerals for rare earth element extraction:

  1. Bastnasite - Primary source of light rare earth elements (LREEs)

  2. Monazite - Important source of LREEs with thorium content

  3. Ion-adsorption clays - Primary source of heavy rare earth elements (HREEs)

  4. Xenotime - Important source of HREEs

  5. Loparite - Secondary source with notable production in Russia

  6. Apatite - Often processed for REEs as a byproduct

  7. Eudialyte - Emerging source with lower processing costs

  8. Fergusonite - Minor source with limited commercial extraction

  9. Zircon - Processed primarily for zirconium with REEs as byproducts

  10. Allanite - Limited commercial extraction

  11. Other minerals (steenstrupine-(Ce), lovozerite, parisite, pyrochlore, gadolinite, etc.) - Currently of minor commercial importance

This ranking reflects both the current production volumes and the economic viability of extraction. The top three minerals (bastnasite, monazite, and ion-adsorption clays) account for approximately 95% of global rare earth production.

Bastnasite: The Premier Light Rare Earth Mineral

Overview and Composition

Bastnasite is a fluorocarbonate mineral with the chemical formula (Ce,La,Nd)(CO3)F. It contains approximately 65-75% rare earth oxides (REO) by weight, making it one of the richest REE-bearing minerals. Bastnasite is paramagnetic with a specific gravity of 4.9-5.2 g/cm³, properties that enable its concentration through magnetic and gravity separation techniques.

Bastnasite deposits are primarily enriched in light rare earth elements (LREEs), with a typical composition of approximately:

  • 30% Lanthanum

  • 50% Cerium

  • 4% Praseodymium

  • 15% Neodymium

  • 1% Other REEs

This mineral is considered the least problematic source of REOs as it contains minimal amounts of radioactive thorium, reducing environmental and regulatory complications associated with extraction.

Key Processing Methodologies

Bastnasite processing typically follows these steps:

  1. Physical Beneficiation: Crushing and grinding followed by flotation to separate bastnasite from gangue minerals.

  2. Chemical Processing: Leaching with acids (typically hydrochloric or sulfuric acid) to dissolve the REEs.

  3. Solvent Extraction: Separation of individual REEs through multiple stages of solvent extraction.

  4. Precipitation: Precipitation of rare earth compounds, typically as carbonates or oxalates.

  5. Calcination: Conversion to rare earth oxides through heating.

At Mountain Pass (USA), the processing begins with crushing in a jaw crusher followed by a cone crusher. The material is then fed to a rod mill producing 1.65-mm material that goes to a classifier in a closed circuit with a conical ball mill. The slurry is heated to 93°C in three agitators and then cooled to 60°C in a fourth agitator before flotation.

Under high-temperature reducing environments, bastnasite decomposes to form stable rare earth oxides and fluorite, which is leveraged in some processing methods.

Economics of Extraction

Bastnasite offers several economic advantages:

  • High REE Content: The high concentration of REEs (65-75% REO) reduces the amount of ore that needs to be processed.

  • Lower Radioactivity: Minimal thorium content reduces costs associated with handling radioactive materials.

  • Established Processing: Well-developed extraction technologies reduce operational risks.

However, challenges include:

  • Capital Intensity: Initial investment for mining and processing facilities is substantial.

  • Energy Requirements: Processing requires significant energy inputs, particularly for crushing, grinding, and heating stages.

  • Chemical Consumption: Large quantities of acids and other reagents are needed.

  • Environmental Compliance: Despite lower radioactivity than some other REE minerals, environmental regulations still impose significant costs.

Major Mining Operations

  1. Bayan Obo Mine (Inner Mongolia, China)

    • World's largest rare earth deposit

    • Produces bastnasite along with monazite and iron ores

    • Accounts for a significant portion of China's 60% share of global REE production

  2. Mountain Pass Mine (California, USA)

    • Operated by MP Materials

    • One of the world's richest bastnasite deposits

    • Ore composition: 60% calcite, 20% barite, 10% bastnasite, and 10% other minerals

    • Resumed operations after closure in the early 2000s

  3. Mount Weld (Australia)

    • Operated by Lynas Rare Earths

    • One of the highest-grade rare earth deposits globally

    • Primarily bastnasite and monazite

These three operations represent the most significant bastnasite mining activities globally, with Bayan Obo being the dominant producer.

Monazite: Phosphate Mineral with Thorium Challenges

Overview and Composition

Monazite is a phosphate mineral with the chemical formula (Ce,La,Nd,Th)PO₄. It typically contains 55-60% REO by weight, making it another rich source of rare earth elements. Like bastnasite, monazite is primarily enriched in light rare earth elements (LREEs), but with a slightly different distribution pattern.

A distinguishing characteristic of monazite is its significant thorium content, which can range from 5-12% ThO₂. This radioactive component presents additional processing challenges and environmental considerations.

Key Processing Methodologies

Monazite processing typically involves:

  1. Physical Concentration: Gravity separation (using spirals, tables, or jigs) and magnetic separation to concentrate the mineral.

  2. Caustic Cracking: Treatment with hot concentrated sodium hydroxide (NaOH) to convert phosphates to hydroxides.

  3. Acid Leaching: Dissolution of rare earth hydroxides in acid (typically hydrochloric acid).

  4. Thorium Removal: Precipitation of thorium as a separate fraction.

  5. Solvent Extraction: Separation of individual REEs.

  6. Precipitation and Calcination: Formation of rare earth oxides.

Alternative processing routes include direct acid leaching with sulfuric acid, but the caustic route is often preferred for its effectiveness in breaking down the phosphate structure.

Economics of Extraction

Monazite presents a mixed economic profile:

Advantages:

  • High REE content (55-60% REO)

  • Often recovered as a byproduct of heavy mineral sand operations, reducing mining costs

  • Contains higher percentages of more valuable heavy REEs than bastnasite

Disadvantages:

  • Thorium content requires specialized handling and disposal, increasing costs

  • Regulatory hurdles related to radioactive material processing

  • Additional processing steps for thorium removal

  • Environmental liabilities associated with radioactive waste management

The economics of monazite processing are heavily influenced by regulations regarding radioactive materials, which vary significantly by country. In some regions, these regulations effectively prevent monazite processing despite the mineral's rich REE content.

Major Mining Operations

  1. Heavy Mineral Sand Operations (Australia, India, Brazil, Malaysia)

    • Monazite is often recovered as a byproduct from titanium and zirconium mining

    • Major producers include Iluka Resources (Australia) and Indian Rare Earths Limited

  2. Mount Weld (Australia)

    • Contains both bastnasite and monazite

    • Operated by Lynas Rare Earths

  3. Bayan Obo (China)

    • Produces monazite alongside bastnasite

    • Integrated processing facilities for both minerals

  4. Steenkampskraal (South Africa)

    • Historical thorium mine with high-grade monazite deposits

    • Under development for renewed production

Monazite production is more geographically distributed than bastnasite, with significant resources in Australia, India, Brazil, Malaysia, and South Africa.

Ion-Adsorption Clays: Critical Source of Heavy Rare Earths

Overview and Composition

Ion-adsorption clays, also known as weathered crust elution-deposited rare earth ores, are a unique source of rare earth elements. Unlike mineral deposits, these clays contain REEs adsorbed onto clay minerals in the form of hydrated ions or hydroxyl hydrated ions. They typically contain only 0.05-0.2% REO by weight—much lower than mineral sources—but are highly enriched in valuable heavy rare earth elements (HREEs).

The clay minerals in these deposits are mainly composed of kaolinite, halloysite, illite, and montmorillonite. The negatively charged structure of these clay minerals allows them to adsorb positively charged rare earth ions.

Key Processing Methodologies

Ion-adsorption clay processing has evolved through three generations of technology:

  1. Pool Leaching (First Generation):

    • Excavation of ore and transportation to leaching pools

    • Leaching with sodium chloride (NaCl) solution

    • Low efficiency and high environmental impact

  2. Heap Leaching (Second Generation):

    • Ore is heaped and leached in place with ammonium sulfate

    • Reduced environmental footprint compared to pool leaching

    • Better suited for ores with many fractures

  3. In-Situ Leaching (Third Generation):

    • Injection of leaching solution directly into the ore body

    • Collection of pregnant solution from wells

    • Minimal surface disturbance

    • Preferred for ores with few fractures and false floors

The leaching agents have also evolved:

  • Initial use of NaCl (sodium chloride) had low efficiency and caused soil salinization

  • Transition to ammonium sulfate reduced salt pollution but introduced ammonia and nitrogen issues

  • Recent development of more environmentally friendly leaching agents

After leaching, the pregnant solution undergoes:

  • Precipitation with oxalic acid or ammonium bicarbonate

  • Calcination to produce rare earth oxides

  • Solvent extraction for separation of individual REEs

Economics of Extraction

Ion-adsorption clays present a unique economic profile:

Advantages:

  • Rich in valuable heavy REEs (dysprosium, terbium, etc.)

  • Simple ion-exchange extraction process

  • Lower capital costs compared to hard-rock mining

  • No crushing or grinding required

  • No radioactive thorium or uranium issues

Disadvantages:

  • Very low grade (0.05-0.2% REO)

  • Large land areas required for economically viable operations

  • Environmental concerns including soil erosion, water contamination

  • Declining grades in existing deposits

The economic viability of these deposits is heavily dependent on the price of heavy REEs, which are typically much more valuable than light REEs. As the primary global source of HREEs, these deposits have strategic importance despite their low overall REE content.

Major Mining Operations

  1. Southern China Provinces (Jiangxi, Fujian, Guangdong, Guangxi)

    • China has a near-monopoly on ion-adsorption clay mining

    • Production is spread across numerous small to medium-sized operations

    • Strict production quotas and environmental regulations implemented in recent years

  2. Potential Developments Outside China:

    • Myanmar (limited production reported)

    • Vietnam (exploration stage)

    • Brazil (research stage)

    • Madagascar (exploration stage)

China's dominance in ion-adsorption clay mining gives it particular control over the global supply of heavy rare earth elements, which has significant strategic implications.

Xenotime: Premium Source of Heavy Rare Earths

Overview and Composition

Xenotime is a yttrium phosphate mineral with the chemical formula YPO₄, though it typically contains significant amounts of other heavy rare earth elements substituting for yttrium. It contains approximately 54-65% REO by weight, with a composition heavily skewed toward heavy rare earth elements—making it particularly valuable despite its relative scarcity.

Xenotime often contains small amounts of uranium and thorium, though typically in lower concentrations than monazite.

Key Processing Methodologies

Xenotime processing shares similarities with monazite processing:

  1. Physical Concentration: Gravity separation and magnetic separation techniques.

  2. Alkaline Cracking: Treatment with concentrated sodium hydroxide to break down the phosphate structure.

  3. Acid Leaching: Dissolution of rare earth hydroxides.

  4. Solvent Extraction: Separation of individual REEs, with particular attention to yttrium and HREEs.

  5. Precipitation and Calcination: Production of rare earth oxides.

Alternative processing routes include direct acid leaching with sulfuric acid, particularly for xenotime recovered as a byproduct from tin mining operations.

Economics of Extraction

Xenotime presents a specialized economic profile:

Advantages:

  • High content of valuable heavy REEs

  • Higher value per ton of concentrate than LREE-dominant minerals

  • Lower thorium content than monazite, reducing radioactive handling issues

Disadvantages:

  • Relatively rare compared to bastnasite and monazite

  • Often found in small deposits or as a byproduct

  • Complex processing requirements

  • Higher processing costs per ton compared to larger-scale operations

The economics of xenotime processing are heavily influenced by the prices of heavy REEs, particularly dysprosium, terbium, and yttrium. As these elements face supply constraints and growing demand from high-tech applications, xenotime's economic importance may increase.

Major Mining Operations

  1. Malaysian Tin Tailings

    • Historical recovery of xenotime as a byproduct of tin mining

    • Declining production as tin resources diminish

  2. Pitinga Mine (Brazil)

    • Xenotime recovered as a byproduct of tin mining

    • One of the few dedicated xenotime recovery operations

  3. Browns Range (Australia)

    • Operated by Northern Minerals

    • One of the few primary xenotime deposits under development

    • Pilot plant operational with plans for full-scale production

  4. Nolans Bore (Australia)

    • Mixed rare earth deposit containing xenotime

    • Under development by Arafura Resources

Xenotime production remains limited compared to bastnasite and monazite, but its importance for heavy REE supply makes it strategically significant.

Loparite: Russian Source of Light Rare Earths

Overview and Composition

Loparite is a complex oxide mineral with the approximate formula (Ce,Na,Ca)(Ti,Nb)O₃. It typically contains 30-35% REO by weight, along with significant amounts of niobium and titanium. Loparite is primarily enriched in light rare earth elements, with a composition somewhat similar to bastnasite.

Key Processing Methodologies

Loparite processing involves:

  1. Physical Concentration: Gravity and magnetic separation techniques.

  2. Chlorination: Treatment with chlorine gas at high temperatures to convert the mineral to chlorides.

  3. Solvent Extraction: Separation of REEs from niobium and titanium, followed by separation of individual REEs.

  4. Precipitation and Calcination: Production of rare earth oxides.

The chlorination process is somewhat unique to loparite processing and allows for the recovery of niobium and titanium as valuable byproducts.

Economics of Extraction

Loparite presents a specialized economic profile:

Advantages:

  • Recovery of valuable byproducts (niobium and titanium)

  • Moderate REE content

  • Established processing technology in Russia

Disadvantages:

  • Limited to specific geological environments

  • Complex processing requirements

  • High energy consumption for chlorination process

The economics of loparite processing benefit significantly from the recovery of niobium and titanium, which offset some of the costs associated with REE extraction.

Major Mining Operations

  1. Lovozero Mine (Kola Peninsula, Russia)

    • Operated by Solikamsk Magnesium Works

    • World's only significant loparite mining operation

    • Integrated processing facility for REEs, niobium, and titanium

Loparite production is essentially limited to Russia, making it a regionally important but globally minor source of rare earth elements.

Eudialyte: Emerging Low-Radioactivity Source

Overview and Composition

Eudialyte is a complex silicate mineral with the approximate formula Na₁₅Ca₆(Fe,Mn)₃Zr₃SiO(O,OH,H₂O)₃(Si₃O₉)₂(Si₉O₂₇)₂(OH,Cl)₂. It typically contains 1-10% REO by weight, along with significant amounts of zirconium. Eudialyte contains both light and heavy rare earth elements, with a more balanced distribution than most other REE minerals.

A key advantage of eudialyte is its very low content of radioactive elements, making it potentially more environmentally friendly than monazite or xenotime.

Key Processing Methodologies

Eudialyte processing is still under development but typically involves:

  1. Physical Concentration: Magnetic separation and flotation.

  2. Direct Leaching: Acid leaching (typically with hydrochloric or sulfuric acid) at moderate temperatures.

  3. Solvent Extraction: Separation of REEs from zirconium, followed by separation of individual REEs.

  4. Precipitation and Calcination: Production of rare earth oxides.

The relatively simple crystal structure of eudialyte makes it amenable to direct leaching without the high-temperature cracking steps required for monazite or xenotime.

Economics of Extraction

Eudialyte presents an emerging economic profile:

Advantages:

  • Very low radioactivity, reducing regulatory and waste management costs

  • Recovery of valuable zirconium as a byproduct

  • Potentially simpler processing compared to phosphate minerals

  • Contains both light and heavy REEs

Disadvantages:

  • Lower REE content than primary minerals like bastnasite

  • Limited commercial processing experience

  • Often found in complex geological settings

The economics of eudialyte processing benefit from the low radioactivity and potential for zirconium recovery, but are challenged by the relatively low REE content.

Major Mining Operations

  1. Kvanefjeld Project (Greenland)

    • Under development by Greenland Minerals

    • Large deposit with significant eudialyte content

    • Advanced stage of planning but facing regulatory challenges

  2. Norra Kärr (Sweden)

    • Under development by Leading Edge Materials

    • One of Europe's most significant heavy REE resources

    • Environmental permitting in progress

  3. Lovozero Massif (Russia)

    • Exploration stage with no commercial production

No commercial-scale eudialyte processing operations currently exist, but several projects are in advanced stages of development, particularly in Europe.

Apatite: Phosphate Mineral with REE Potential

Overview and Composition

Apatite is a calcium phosphate mineral with the formula Ca₅(PO₄)₃(F,Cl,OH). While primarily mined for phosphate fertilizer production, some apatite deposits contain significant REE content, typically 0.1-1% REO by weight. The REE distribution in apatite is generally weighted toward light rare earths.

Key Processing Methodologies

REE recovery from apatite typically occurs as a byproduct of phosphoric acid production:

  1. Phosphoric Acid Production: Treatment of apatite with sulfuric acid to produce phosphoric acid and phosphogypsum.

  2. REE Extraction from Acid: Solvent extraction or ion exchange to recover REEs from the phosphoric acid stream.

  3. Alternative Route: Direct leaching of apatite with nitric acid, followed by solvent extraction.

  4. Precipitation and Calcination: Production of rare earth oxides.

The integration with phosphoric acid production provides economic synergies but also introduces complexities in process optimization.

Economics of Extraction

Apatite presents a specialized economic profile for REE recovery:

Advantages:

  • REE recovery as a byproduct of phosphate fertilizer production

  • Existing mining and processing infrastructure

  • No additional mining costs when integrated with phosphate production

  • Low radioactivity compared to monazite

Disadvantages:

  • Low REE content

  • Complex integration with phosphoric acid production

  • Process modifications required for existing phosphate plants

  • Capital costs for REE recovery circuits

The economics of REE recovery from apatite are heavily dependent on integration with phosphate fertilizer production and typically require high REE prices to be economically viable as a standalone process.

Major Mining Operations

  1. Kola Peninsula (Russia)

    • Operated by PhosAgro

    • Integrated phosphate and REE recovery

    • One of the world's largest apatite mining operations

  2. Siilinjärvi Mine (Finland)

    • Operated by Yara

    • Potential for REE recovery under investigation

  3. Florida Phosphate District (USA)

    • Multiple operations by Mosaic and others

    • Historical studies on REE recovery, but limited implementation

While many phosphate operations worldwide have potential for REE recovery, commercial implementation remains limited due to economic and technical challenges.

Fergusonite: Niobium-Tantalum-REE Mineral

Overview and Composition

Fergusonite is a mineral of the formula (Y,REE)NbO₄, where REE represents rare earth elements. It typically contains 30-50% REO by weight, with a composition heavily weighted toward yttrium and heavy rare earths. Fergusonite often contains significant amounts of niobium and tantalum, as well as variable amounts of uranium and thorium.

Key Processing Methodologies

Fergusonite processing is not well-established at commercial scale but typically involves:

  1. Physical Concentration: Gravity separation and magnetic separation.

  2. Alkaline Decomposition: Treatment with concentrated sodium hydroxide.

  3. Acid Leaching: Dissolution of rare earths and niobium/tantalum.

  4. Solvent Extraction: Separation of REEs from niobium and tantalum, followed by separation of individual REEs.

  5. Precipitation and Calcination: Production of rare earth oxides.

The processing shares similarities with other refractory minerals but must account for the niobium and tantalum content.

Economics of Extraction

Fergusonite presents a specialized economic profile:

Advantages:

  • High content of valuable heavy REEs

  • Recovery of niobium and tantalum as byproducts

  • High value per ton of concentrate

Disadvantages:

  • Relatively rare and typically found in small deposits

  • Variable uranium and thorium content requiring specialized handling

  • Limited commercial processing experience

  • Complex multi-element separation requirements

The economics of fergusonite processing are challenged by the mineral's relative rarity and the complex processing requirements, but supported by the high value of contained heavy REEs and niobium/tantalum.

Major Mining Operations

  1. Nechalacho (Canada)

    • Under development by Vital Metals

    • Contains fergusonite among other REE minerals

    • Early stage production focusing on other minerals initially

  2. Madagascar

    • Artisanal mining of fergusonite from pegmatites

    • Small-scale, non-industrial production

No significant commercial-scale fergusonite mining operations currently exist, though the mineral is occasionally recovered as a byproduct from pegmatite mining.

Zircon: Zirconium Mineral with REE Content

Overview and Composition

Zircon is a zirconium silicate mineral with the formula ZrSiO₄. While primarily mined for zirconium, some zircon contains significant REE content, typically 0.1-5% REO by weight. The REE distribution in zircon is variable but often includes elevated levels of heavy rare earths.

Key Processing Methodologies

REE recovery from zircon is not widely practiced but would typically involve:

  1. Physical Concentration: Gravity separation from heavy mineral sands.

  2. Alkaline Fusion: Treatment with sodium hydroxide at high temperatures.

  3. Acid Leaching: Dissolution of rare earths and zirconium.

  4. Solvent Extraction: Separation of REEs from zirconium, followed by separation of individual REEs.

  5. Precipitation and Calcination: Production of rare earth oxides.

The primary focus of zircon processing is typically zirconium recovery, with REEs as a potential byproduct.

Economics of Extraction

Zircon presents a specialized economic profile for REE recovery:

Advantages:

  • REE recovery as a byproduct of zirconium production

  • Existing mining and processing infrastructure for heavy mineral sands

  • Low additional mining costs when integrated with zirconium production

Disadvantages:

  • Low and variable REE content

  • Complex processing requirements for REE recovery

  • Primary economic driver is zirconium, not REEs

  • Limited commercial implementation

The economics of REE recovery from zircon are heavily dependent on integration with zirconium production and typically require high REE prices to be economically viable.

Major Mining Operations

  1. Heavy Mineral Sand Operations (Australia, South Africa, India)

    • Multiple operations by Iluka Resources, Rio Tinto, and others

    • Primary focus on zirconium with limited REE recovery

  2. Dubbo Project (Australia)

    • Under development by Australian Strategic Materials

    • Plans for integrated zirconium and REE recovery

While many zircon mining operations exist worldwide, commercial REE recovery from zircon remains limited.

Allanite: Complex Silicate with REE Potential

Overview and Composition

Allanite is a complex silicate mineral with the approximate formula (Ce,Ca,Y)₂(Al,Fe)₃(SiO₄)₃(OH). It typically contains 15-30% REO by weight, primarily light rare earths. Allanite often contains significant amounts of thorium and sometimes uranium, presenting radiological challenges.

Key Processing Methodologies

Allanite processing is not well-established at commercial scale but typically involves:

  1. Physical Concentration: Gravity and magnetic separation.

  2. Roasting: Oxidation of iron and rare earths.

  3. Acid Leaching: Dissolution of rare earths, typically with sulfuric acid.

  4. Solvent Extraction: Separation of individual REEs.

  5. Precipitation and Calcination: Production of rare earth oxides.

The high iron content of allanite presents challenges for selective leaching of rare earths.

Economics of Extraction

Allanite presents a specialized economic profile:

Advantages:

  • Moderate REE content

  • Widespread occurrence in small quantities

Disadvantages:

  • Variable thorium content requiring specialized handling

  • Complex mineralogy complicating processing

  • High iron content interfering with REE recovery

  • Limited commercial processing experience

The economics of allanite processing are challenged by the complex mineralogy and potential radiological issues, making it currently a minor source of REEs.

Major Mining Operations

No significant commercial-scale allanite mining operations currently exist specifically for REE recovery, though the mineral is occasionally encountered as an accessory mineral in other mining operations.

Other Rare Earth Minerals of Limited Commercial Importance

Several other minerals contain significant REE content but are of limited commercial importance due to rarity, complex processing requirements, or economic factors:

Steenstrupine-(Ce)

  • Complex silicate-phosphate mineral

  • Found primarily in Greenland's Ilímaussaq complex

  • No commercial production

Lovozerite

  • Complex silicate mineral

  • Found in the Lovozero massif, Russia

  • No commercial REE production

Parisite

  • Fluorocarbonate mineral related to bastnasite

  • Occasionally found in carbonatite deposits

  • Limited commercial production

Pyrochlore

  • Complex oxide mineral primarily mined for niobium

  • Some varieties contain significant REEs

  • Limited REE recovery as a byproduct of niobium production

Gadolinite

  • Silicate mineral rich in yttrium and heavy REEs

  • Found in pegmatites

  • Historical importance but limited modern production

Yttrofluorite

  • Fluorite with yttrium substitution

  • Rare mineral with limited distribution

  • No commercial production

Yttrocerite

  • Variety of fluorite containing yttrium

  • Very limited occurrence

  • No commercial production

These minerals may become more economically significant as technology advances or if supply constraints develop for the primary REE minerals.

Environmental and Geopolitical Considerations

Environmental Impacts

The extraction and processing of rare earth minerals present significant environmental challenges:

  • Radioactive Waste: Minerals like monazite contain thorium and uranium, requiring specialized waste management. For every ton of rare earth produced, the mining process yields approximately one ton of radioactive residue.

  • Chemical Pollution: Processing typically involves strong acids, bases, and organic solvents. The mining process produces approximately 75 cubic meters of wastewater per ton of REE.

  • Air Pollution: REE processing generates approximately 9,600-12,000 cubic meters of waste gas and 13kg of dust per ton of product.

  • Land Disturbance: Open-pit mining and in-situ leaching can lead to vegetation loss, soil erosion, and ecosystem disruption.

  • Water Contamination: Leaching operations, particularly for ion-adsorption clays, risk contaminating groundwater and surface water.

China's State Council has acknowledged that the nation's rare earth industry has inflicted "intense harm to the ecological environment, resulting in vegetation loss and contamination of surface water, groundwater, and agricultural land."

Geopolitical Factors

The rare earth supply chain has significant geopolitical implications:

  • Chinese Dominance: China accounts for approximately 60% of global mine production and 90% of processed output and permanent magnet production. In 2023, China produced 242,000 metric tons out of an estimated global total of 350,000 metric tons.

  • Export Restrictions: China has implemented various export restrictions, including a 2023 ban on exporting technologies for rare earth processing and stricter regulations on domestic mining, smelting, and trading effective October 2024.

  • Supply Chain Vulnerabilities: The concentration of production and processing in China creates vulnerabilities for industries in other countries, particularly in defense and high-technology sectors.

  • Strategic Responses: Countries including the United States, Australia, and European nations are working to develop alternative supply chains, though progress has been limited by economic and technical challenges.

  • Price Volatility: The concentrated supply chain contributes to price volatility, with significant price declines observed in 2024 affecting industry profitability.

Future Outlook and Emerging Technologies

Recycling and Urban Mining

Recycling represents a potential alternative source of rare earth elements:

  • IDTechEx forecasts that by 2045, approximately 3.3 million tonnes of critical materials will be recovered from secondary sources, equivalent to over US$110 billion in valuable materials.

  • Current recycling rates remain below 1% due to technical challenges including low concentrations in end products and difficulties separating individual REEs.

  • Recycling itself requires significant energy and can generate hazardous waste, limiting its environmental benefits.

Technological Innovations

Several technological innovations may impact the rare earth industry:

  • Bio-leaching: Use of microorganisms to extract rare earths from ores with potentially lower environmental impact.

  • In-situ Recovery: Advanced techniques for recovering REEs without traditional mining, potentially reducing surface disturbance.

  • Advanced Separation Technologies: Development of more efficient and environmentally friendly separation processes.

  • Substitution: Research into alternative materials that could reduce dependence on certain rare earth elements.

Market Dynamics

The rare earth market continues to evolve:

  • Price Volatility: Significant price declines were observed in 2024, with dysprosium losing 30% of its value, terbium down by 27%, and neodymium-praseodymium falling by 17%.

  • Production Growth: Global rare earth output has rapidly risen from 240,000 metric tons in 2020 to 350,000 metric tons in 2023, with an estimated 390,000 metric tons in 2024.

  • Demand Drivers: Electric vehicles, wind turbines, and consumer electronics continue to drive demand growth, particularly for neodymium, praseodymium, dysprosium, and terbium used in permanent magnets.

  • Supply Diversification: Efforts to develop rare earth production outside China continue, though China's dominance remains unchallenged in the near term.

Conclusion

The economic extraction of rare earth elements relies primarily on three mineral sources—bastnasite, monazite, and ion-adsorption clays—which together account for approximately 95% of global production. These minerals have distinct characteristics that influence their economic viability, processing requirements, and environmental impacts.

Bastnasite dominates as the primary source of light rare earth elements, with major production centers in China and the United States. Monazite provides an important secondary source of light REEs but faces challenges related to its thorium content. Ion-adsorption clays, found almost exclusively in southern China, represent the primary source of heavy rare earth elements despite their low overall REE content.

Other minerals including xenotime, loparite, and eudialyte have more limited commercial importance but may play increasing roles as technology advances and supply diversification efforts continue.

The rare earth industry faces significant environmental challenges, including radioactive waste management, chemical pollution, and ecosystem disruption. These challenges, combined with the concentrated nature of the supply chain, create both economic and geopolitical complexities that will continue to shape the industry's development.

As global demand for rare earth elements continues to grow, driven by clean energy technologies and advanced electronics, the development of more sustainable and geographically diverse supply chains remains a critical challenge for the industry and for technology-dependent economies worldwide.

Sources

USGS

Statistics and information on the worldwide supply of, demand for, and flow of the mineral commodity group rare earths - scandium, yttrium, and the lanthanides

The principal economic sources of rare earths are the minerals bastnasite, monazite, and loparite and the lateritic ion-adsorption clays. The rare earths are a relatively abundant group of 17 elements composed of scandium, yttrium, and the lanthanides. The elements range in crustal abundance from cerium, the 25th most abundant element of the 78 common elements in the Earth's crust at 60 parts per million, to thulium and lutetium, the least abundant rare-earth elements at about 0.5 part per million.

ScienceDirect

This article addresses the question of how the global and U.S. market sector allocations for rare earth elements compare.

Supplies depend upon resources; bastnasite and monazite deposits are rich in the light rare-earth elements (LREEs), whereas xenotime ion-adsorption clays (predominant in China) are rich in the heavy rare-earth elements (HREEs). Meanwhile demand is determined by REE allocations across the varied market sectors. Diversified REE resources with higher concentrations of critical elements is a potential solution, pending identification at needed scales.

Nasdaq

Rare earths prices saw some gains in May 2024, fueled by positive sentiment over consumer demand in China.

The principal economic sources of rare earths are the minerals bastnasite, monazite, and loparite and the lateritic ion-adsorption clays. Globally, China holds a predominant position in the REE sector, not only in terms of reserves but also in processing capabilities. The Bayan Obo mine in Inner Mongolia is one of the world's largest known REE deposits.
Global rare earths output has rapidly risen from 240,000 metric tons in 2020 to 350,000 metric tons in 2023, according to US Geological Survey data. The lion's share of rare earth production continues to be dominated by China, a factor that remains relevant for the industry as the Asian nation continues to flex its control.
In late 2023, China imposed bans on exporting technologies for rare earths processing, tightening its grip on the global supply chain. By mid-2024, reports were circulating that the country's State Council would introduce stricter regulations on domestic rare earths mining, smelting and trading, effective October 1, 2024. The rules would declare rare earth resources state-owned and require companies to maintain detailed records in a traceability system.

Fastmarkets

Insight into the rare earths industry, price trends, and market outlook for 2025

Falling prices have been the dominant theme in the rare earths industry in 2024. A steep slump at the start of the year capped two years of price declines that have slashed profits and upended processing margins. Prices for magnetic raw materials dropped in unison at the start of the year. By the summer, dysprosium had lost 30% of its value, terbium was down by 27%, and neodymium-praseodymium (NdPr) had fallen by 17%.

ScienceDirect

A scientific reference page about the mineral bastnasite and its properties

Bastnasite is a mineral that, under high temperature reducing environments, decomposes to form stable rare earth oxides and fluorite. Bastnasite ores contain mostly rare earths near the beginning of the series, La, Ce, Pr, and Nd. For a typical deposit the figures would be approximately 30% La, 50% Ce, 4% Pr, and 15% Nd, leaving the remaining elements at the 1% level.
Bastnäsite is a fluorocarbonate mineral involving about 65–75 wt% REO depending on the deposit. It is a paramagnetic mineral with a specific gravity of about 4.9–5.2 (g/cm3). These properties enable it for magnetic and gravity concentration techniques.

Springer

A scientific article analyzing the material and energy requirements for rare earth metal production

Bastnäsite ores (Ce,La,Nd)(CO3)F are fluorocarbonates of cerium, lanthanum, neodymium, and other REMs. They occur in carbonatites, quartz veins, and epithermal fluorite-bearing veins. The world's largest deposit is at Bayan Obo in Inner Mongolia, where bastnäsite occurs together with monazite and other iron-bearing ores. Bastnäsite is the least problematic source of REO, as it hardly contains any radioactive thorium.
About 95% of REMs occur in three minerals: bastnäsite, monazite, and xenotime. The larger rare earth mine is located in Bayan Obo (China) and Mountain Pass (United States). In Mountain Pass, the principal minerals occurring are 60% calcite (CaCO3), 20% barite (BaSO4), 10% bastnäsite, and the remaining 10% of other minerals such as silica (SiO2).

Britannica

An encyclopedia entry detailing the processing of rare earth element ores

At Mountain Pass, the primary ore is crushed in a jaw crusher in series with a cone crusher and then to a rod mill, which produces a 1.65-mm material that is later fed to a classifier in a closed circuit with a conical ball mill. The classifier feeds the material to four agitators. The first three agitators heat the slurry up to 93°C, whereas the fourth cools the slurry to 60°C. Subsequently, the granules are sent to flotation.

ScienceDirect

A review of rare earth element extraction methods from ionic clays, focusing on sustainable and environmentally friendly techniques

Historically, traditional methods of extracting rare earths from mineral ores have been environmentally detrimental and economically intensive due to their complex multi-step procedures and the handling of radioactive materials. In contrast, ionic clays, primarily found in weathered crusts of granite and volcanic rocks, offer a more accessible source of rare earths, particularly heavy rare earth elements (HREEs), through simpler ion exchange processes.

Eos

An exploration of rare earth elements, their applications, and future sustainability in technology and manufacturing

Rare earth elements (REEs) are essential components of more than 200 products, especially high-tech consumer products, such as cellular telephones, computer hard drives, electric and hybrid vehicles, and flat-screen monitors and televisions. For example, headphone technologies and the ability to design them smaller is possible because of strong neodymium magnets in them.

GlobeNewswire

A press release detailing USA Rare Earth's successful production of high-purity dysprosium oxide using proprietary extraction technology

USA Rare Earth successfully produced a sample of dysprosium oxide (Dy₂O₃) with a purity of 99.1 wt.%. The dysprosium oxide sample was produced using ore from the Texas Round Top deposit and USA Rare Earth's proprietary rare earth extraction and purification technology, developed at the Company's Wheat Ridge, Colorado research facility.

TechConnect World

A symposium focused on innovative strategies for critical material recovery from sustainable sources

With increasing global demand for critical materials and growing uncertainties in supply chains, the 'Innovative Strategies for Critical Material Recovery from Sustainable Feedstocks' symposium will bring together industry leaders, academic researchers, and national laboratory experts.

IDTechEx

A research report analyzing the market for critical material recovery from secondary sources, including technologies, forecasts, and market potential

IDTechEx forecasts that by 2045, approximately 3.3 million tonnes of critical materials will be recovered from secondary sources, equivalent to over US$110B in valuable materials. Secondary raw materials, including end-of-life equipment, automotive vehicles, electric vehicles, e-waste and waste scrap, represent a rapidly emerging source of valuable critical materials.

Statista

Global statistics on rare earth elements mine production, showing growth from 133,000 to 390,000 metric tons between 2010 and 2024

Globally, the total mine production of rare earth elements more than doubled between 2010 and 2024. From approximately 133,000 metric tons of rare-earth-oxide (REO) content produced in 2010, rare earths production grew to an estimated 390,000 metric tons of REO content in 2024.
China and the United States are the world's leading rare earths producing countries. China accounts for about 60% of global mine production and 90% of processed and permanent magnet output. Beijing sets quotas on output, smelting, and separation, which are closely monitored as a barometer of global supply.

Reuters

Comprehensive overview of rare earth metals, their composition, uses, and global significance

Rare earths are a group of 17 elements including 15 silvery-white metals called lanthanides, or lanthanoids, plus scandium and yttrium. They are used in a wide range of products including consumer electronics, electric vehicles (EVs), aircraft engines, medical equipment, oil refining, and military applications such as missiles and radar systems.
They are not rare in the sense that they are uncommon; some are more common than lead, for example. But they tend to be spread thin around the Earth's crust in small quantities and mixed together or with other minerals, so larger deposits are difficult to find and costly to extract. Processing rare earths often involves the use of solvents, which can produce toxic waste that pollutes the soil, water, and atmosphere. More environmentally friendly technologies are being developed, but they are not yet widely used.

ScienceDirect

A scientific review examining the environmental impacts and extraction processes of rare earth elements

Rare earth elements (REEs) are vital for the technology, military, and defense industries. They have been recognized as critical due to potential scarcity, supply constraints, and lack of minable concentrations. However, the environmental prospect of rare earth mining was not investigated enough, and comprehensive studies are lacking. It demands serious consideration as toxic radionuclides are seen in the same mineralization as rare earths regardless of their primary or secondary sources.
For every ton of rare earth produced, the mining process yields 13kg of dust, 9,600-12,000 cubic meters of waste gas, 75 cubic meters of wastewater, and one ton of radioactive residue. This stems from the fact that rare earth element ores have metals that, when mixed with leaching pond chemicals, contaminate air, water, and soil. Most worrying is that rare earth ores are often laced with radioactive thorium and uranium, which result in especially detrimental health effects.

Harvard International Review

An in-depth exploration of the environmental and social impacts of rare earth element mining

Most people view technology as the future, a force of good that will generally improve quality of life around the world. In the business sector, Silicon Valley and tech startups exhibit massive growth potential; in manufacturing, new machinery and automation are boosting efficiency; and in the environmental realm, green technology presents the best prospects for decarbonization. But as much as technology is hailed as the panacea of the future, most of these innovations have a dirty underside: production of these new technologies requires companies to dig up what are referred to as rare earth elements (REEs).
There are two primary methods for REE mining, both of which release toxic chemicals into the environment. The first involves removing topsoil and creating a leaching pond where chemicals are added to the extracted earth to separate metals. This form of chemical erosion is common since the chemicals dissolve the rare earth, allowing it to be concentrated and then refined. However, leaching ponds, full of toxic chemicals, may leak into groundwater when not properly secured and can sometimes affect entire waterways.

Institute for Policy Studies

A comprehensive analysis of the global environmental and social challenges surrounding rare earth element extraction

REEs are usually present in very low concentrations and are combined; this means that their extraction and separation are expensive, require large amounts of energy and water, and generate large quantities of waste. Moreover, they are often mixed with different radioactive and hazardous elements such as uranium, thorium, arsenic and other heavy metals which pose high health and environmental pollution risks. Extraction methods include open-pit mining (generally involving intense water usage), underground and in-situ leaching.
While there are high expectations regarding REE recycling, this remains a marginal source (less than 1%). There are many obstacles to REE recycling, such as the low concentration of end-products and the difficulty inherent in separating individual REEs from each other. Recycling is also far from being a clean industry, as it requires large amounts of energy and generates hazardous waste.

Circularise

An exploration of the environmental, economic, and supply chain challenges in rare earth element production

REEs are extracted through extensive open-pit mining, a process that not only consumes high amounts of energy, but can also lead to environmental issues such as water pollution and radioactive waste, and the disruption of ecosystems. Already in 2010, China's State Council acknowledged that the nation's rare earth industry was inflicting 'intense harm to the ecological environment, resulting in vegetation loss and contamination of surface water, groundwater, and agricultural land.' The council attributed landslides and blocked rivers to the excessive mining of rare earth elements.
As the environmental footprint of products becomes increasingly important, understanding and tracking the product's entire life cycle is crucial. This could reveal, for instance, whether the REEs in a product are legally sourced from mines with fair working conditions, among other things. Unfortunately, this information is not appropriately documented or shared within REE value chains. This is due to the absence of traceability practices among stakeholders and privacy concerns that deter companies from disclosing sensitive data.

East Asia Forum

Peer reviewed analysis from world leading experts on China's strategic use of critical minerals in global trade

China's export restrictions on critical minerals like gallium and germanium reflect its geopolitical strategy, mirroring past actions with rare earths. These materials are crucial for semiconductors, electric batteries and defence technologies. In response to US semiconductor sanctions, China is flexing its dominance over global critical minerals supply chains, intensifying trade tensions.

Area Development

Analysis of U.S. challenges in reducing reliance on China for rare earth minerals and supply chains

As the world grows increasingly reliant on technology, the United States faces an urgent challenge: breaking China's dominance in the rare earth supply chain. Rare earth elements (REEs)—critical components in electric vehicles (EVs), wind turbines, and defense technologies—are abundant in the Earth's crust but notoriously difficult to mine and process. For decades, China has controlled the majority of that supply chain, leaving the U.S. and other nations dependent on Beijing for these essential materials.

CSIS China Power Project

Comprehensive analysis of China's role and dominance in global rare earth mineral trade and supply chains

From 2008 to 2018, China exported nearly 408,000 metric tons of rare earths, which amounted to 42.3 percent of all rare earth exports over the period. The United States was the second-largest exporter, supplying roughly 9.3 percent of the global total. Malaysia (9.1 percent), Austria (9.0 percent), and Japan (7.1 percent) rounded out the top five.

Fridtjof Nansen Institute

Research project examining China's role in critical minerals supply chains and its implications for Norway

China, the world's second largest economy, plays a central role in supply chains of critical minerals and metals. As a member of the World Trade Organization, China is well integrated into global supply chains, which include critical metals and minerals. China has specialized in the extraction and processing of critical minerals which has made the country the most dominant player on the world market, with a near monopoly on access to some resources (especially heavy rare earths) which are necessary for most technological-industrial activities.

Debug Lies News

In-depth analysis of China's economic dominance, focusing on supply chains, rare earth minerals, innovation, and global economic strategies

In 2023, China accounted for 69.2% of global rare earth oxide (REO) production, totaling 242,000 metric tons out of an estimated 350,000 metric tons worldwide. This dominance extends to processing, where China refines nearly 90% of the world's rare earths, a figure corroborated by the U.S. Geological Survey.

MDPI

A review of leaching technologies and agents for weathered crust elution-deposited rare earth ores, focusing on technological advancements, environmental considerations, and extraction methods.

Weathered crust elution-deposited rare earth ores are key strategic resources and the main source of medium and heavy rare earths. This paper summarizes the development of leaching technology of rare earth ores, compares the advantages and disadvantages of the three generations of leaching technology, and introduces the improved heap leaching technology and the new technology of the leaching–extraction integration and enhanced leaching, focusing on the leaching of weathered crust elution-deposited rare earth ores.
Rare earth ores are mainly divided into mineral-type rare earth ores and weathered-type rare earth ores (also known as ion adsorption rare earth ores). Mineral-type rare earth ores are the main source of light rare earths and are mainly represented by fluorocarbon ores, which can be recovered and enriched by gravity separation, magnetic separation, and flotation, while the weathered crust elution-deposited rare earth ores are adsorbed on clay minerals in the form of hydrated ions or hydroxyl hydrated ions, which are the main source of medium and heavy rare earths and can only be recovered and enriched by ion exchange.
For the mining of weathered crust elution-deposited rare earth ores, China has successively developed three generations of rare earth leaching technologies, such as pool leaching, heap leaching, and in situ leaching. The heap leaching and in situ leaching technologies are developed on the basis of the pool leaching technology, which are suitable for large-scale rare earth mining. Rare earth ores with different ore body structures are suitable for different leaching technologies. For rare earth ores with false floors and few ore body fractures, the in situ leaching technology is favored; otherwise, the heap leaching technology is a better option.
Initially, NaCl was used as the rare earth leaching agent, but the rare earth leaching efficiency was low, and the use of high-concentration NaCl also generated the high-salt wastewater that would cause soil salinization and environmental pollution. In order to solve the shortcomings of the NaCl leaching agent, researchers developed an ammonium sulfate leaching agent, which solved the pollution problem of high-salt waste residue and wastewater; however, the ammonium sulfate leaching agent also produced problems such as ammonia and nitrogen pollution and a high impurity content in the leachate.
The weathered crust elution-deposited rare earth ores contain a large amount of clay minerals, and the clay minerals are mainly silicate minerals with a layered structure, which are composed of negatively charged silicon – oxygen tetrahedrons and aluminum – oxygen octahedrons, a phenomenon in which low-valent cations replace high-valent cations, thereby making the clay sheets negatively charged. The clay minerals in weathered crust elution-deposited rare earth deposits are mainly composed of kaolinite, halloysite, illite, montmorillonite, etc., among which kaolinite and halloysite are composed of silica tetrahedrons and alumina octahedrons at a ratio of 1:1.

 
 
 

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